HUANG Qizhong
,
YANG Qzaoqin and WU Lijun(Powder Metallurgy Research institute
,
Central Sonth University of Technology
,
Changsha 410083
,
China Materials Research and Test Center
,
Hnnan University
,
Changsha 410082
,
ChinaLab. of Atomic Imaging of Solids
,
Institute of Metal Research
,
Chinese Academy of Sciences
,
Shenyang110015
,
ChinaState Key Laboratory for Corrosion and Protection
,
Institute of Corrosion and Protection of Metals
,
Chinese Academy of Sciences
,
Shenyang 110015
,
China)Manuscript received 4 August 1995
,
in revised form 6 April 1996
金属学报(英文版)
A Preliminary study of the effect of silicon additive on the structure and properites of C-B_4C-SiC composite was conducted. A liquid Phase has formed and the liquid Si reacts with C to form SiC at the grain boundary when sintering, which accelerates the sintering process and retards the grain growth. Consequently, the density and strength of the composite increase markedly. And the increase in the density increases the oxidation resistance and decreases the specific resistance of the composite. Furthermore,the C-B_4 C-SiC composite has good heat-shock resistance. The phenomena may be dueto the strengthening and toughening of microcracks.
关键词:
:Si additive
,
null
,
null
NIU Yan
,
F.GESMUNDO
,
WU Weitao
,
ZENG Chaoliu
,
F.VIANI
,
(State Key Laboratory for Corrosion and Protection
,
Institute of Corrosion and Protection of Metals
,
Chinese Academy of Sciences
,
Shenyang.110015
,
China)(Istituto di Chimica
,
Facolta'di Ingegneria
,
Universita'di Genova
,
Fiera del Mare
,
Pad.D
,
16129 Genova
,
Italy)Manuscript received 3 July 1995
金属学报(英文版)
The corrosion properties of a Co-15wt% Y alloy were studied in H_2-H_2S mixtures under a sulfur pressure of 10-3 Pa at 600-800℃ and of 10-2 Pa at 800℃ to examine the effect of Y on the resistance of pure cobalt to sulfur attack at high temperatures.The alloy is nearly single-phase.containing mostly the intermetallic compound Co17Y2 plus a little amount of the solid solution of Y in cobalt.At 600-700℃ and at 800℃ under 10-2 Pa of S2 the alloy forms multi-layered scales consisting of an outer region of pure cobalt sulfide,an intermediate region of a mixture of the sulfides of the two metals and finally an innermost layer of a mixture of yttrium sulfide with metal cobalt.At 800℃ under 10-3Pa of S2,below the dissociation pressure of cobalt sulfide, the alloy forms only a single layer composed of a mixture of metallic cobalt with yttrium sulfide.Pure Y produces only the oxysulfide Y2O2S, as a result of the good stability of this compound and of the presence of some impurities in the gas mixtures used The corrosion kinetics is generally rather complex and irregular except al 800℃under 10-3 Pa of S2.The addition of yttrium always reduces the sulfidation rate of cobalt, even though the formation of a continuous protective external layer of yttrium sulfide is never achieved.The internal sulfidation of Y in Co-15% Y is not associated with a depletion of Y in the alloy.This kind of diffusionless internal attack is typical of alloys with a very small solubility of the most reactive component Y in the base metal A.which restricts severely the Y flux from the alloy towards the alloy-scale interface.
关键词:
:cobalt-yttrium alloy
,
null
,
null
LI Hiaogang
,
MENG Qinghai
,
CHEN Hua
,
CHEN Jinwei
,
YAO Zhiming
,
KE Wei(State Key Laboratory of Corrosion Science
,
Institute of Corrosion and Protection of Metals
,
Chinese Academy of Sciences
,
Shenyang 110015
,
China)(Fushun Petroleum Institute
,
Fushun 113001
,
China)
金属学报(英文版)
Hydrogen attack occurred in low carbon steel and steel 25CrMo which had been exposed in hydrogen under 18MPa at 450 and 500℃ for 240,480 and 720 h.The methane bubbles and microcracks grow along grain boundaries.The degree of hydrogen attack increases with increasing exposure time and temperature.Magnetic acoustic emission(MAE) was used to detect the degree of hydrogen attack.The results show that the characteristics of MAE for samples of low carbon steel and steel 15CrMo with hydrogen attack have changed obviously comparing to the samples without hydrogen attack,and the MAE signals was sensitive to the degree of hydrogen attack at the last stage of hydrogen attack.The magnetic detection way,as a new method of nonrestrictive testing of hydrogen attack,can be used to detect the hydrogen attack in practice.
关键词:
:magnetic acoustic emission
,
null
,
null
,
null
ZHANG Cheng
,
WANG Yongzhong
,
JIANG Ming
,
ZENG Dechang
,
TANG Hong
,
LI Zhongrun
,
QIAO Guiwen
,
CHUANG Yuzhi(Institute of Metal Research
,
Chinese Academy of Sciences
,
Shenyang
,
ChinaManuscript received on 20 April 1995)
金属学报(英文版)
Bi-2212 superconductive oxides with nanometer grains have been prepared by means of crystallization from amorphous materials.The structure and grain-size of samples were examined by.X-ray.diffraction,scanning electron microscopy.and high resolution electron microscopy.The temperature dependence of the resistivity.and a.c.susceptibility was measured by the standard four-probe method and the standard mutual-induction measurement,respectively.With the decrease of temperature,the resistivity of the Bi-2212 phase with grain size in nanometer was found to diminish to zero without sudden drop.No diamagnetic transition was detected from room temperature to 4.2 K.The formation of the nanocrystalline 2212 phase and the effect of grain size on the superconductivity were discussed.
关键词:
:Bi-2212
,
null
,
null
,
null
LI Gang
,
WANG Zhongguang
,
LI Guangyi(State Key Laboratory of Fatigue and Fracture for Materials
,
Institute of Metal Research
,
Chinese Academy of Sciences
,
Shenyang 110015
,
China)V.OVCHARENKO(Institute of Strength Physics and Materials Science
,
Russian Academy of Science
,
Siberian Branch
,
Tomsk
,
Russia) Manuscript received 3 May 1995
金属学报(英文版)
Self propagating high temperature synthesis(SHS) under compression was utilized to obtain an intermetallic compound Ni_3 Al by using elemental powders.The microstructure of the SHS product was observed by optical microscopy(OM) and scanning electron microscopy(SEM).The results reveal that the SHS Ni3Al is a single-phase polycrystalline alloy wilh LI2 crystal structure.Tensile tests were conducted from room temperature to 800℃ both in air and in vacuum.The results show that the SHS Ni_3Al exhibits an anomalous temperature dependence of ultimate tensile strength.The ultimate tensile strength in vacuum is much higher than that in air over the whole temperature range.Fracture surfaces are characterized by the brittle grain boundary fracture and the intergranular fracture mode can not be affected markedly by the test environment.
关键词:
:Ni_3Al
,
null
,
null
,
null
JIN Man
,
JIANG Zhonghao
,
NAN Shenghui
,
HU Jiandong
,
LIAN jianshe(Jilin University of Technology
,
Changchun
,
China)(Manuscript received 8 February 1995)Correspondent:LI Geping
,
(Institute of Metal Research
,
Chinese Academy of Sciences
,
Shenyang 110015
,
China)
金属学报(英文版)
The low carbon dual phase structure was cold de formed first,then was tempered at 200 to 600℃.The variation in strength and ductility during tempering of the steel was investigated.It was found that a fter the de formed dual phase structure was tempered at 200 to 600℃, with the increase in the tempering temperature the tensile strength decreases rapidly;the lotal elongation remains constant at 200 to 500℃ but began to rise dramatically at a critical temperature between 500 and 600℃.However,when the non-deformed dual phase structure was tempered at the same temperature range,the tensile strength decreases and the total elongation increases continuously with the increase of temperature.It was demonstrated from TEM analysis that precipitating carbides density along the boundaries ofmartensite lath and the recrystallized grains are responsible for the tempering response ofthe de formed dual phase structure.
关键词:
:de formed dual phase structure
,
null
,
null
WU Zhixue
,
XU Hao(Institute of Mechanical Engineering
,
Northeastern University
,
Shenyang 110006
,
China)(Fushun Petroleum institute
,
Fushun 113001.China).(State Key Laboratory for Fatigue and Fracture of Materials
,
Institute of Metal Research
,
Chinese Academy of Sciences
,
Shenyang 110015
,
China) Manuscript received 2 July 1995
金属学报(英文版)
Rotary bending fatigue tests were carried out using smooth specimens of a medium-carbon steel with two different grain sizes.The process of early crack development was observed by the replica method,and the effects of grain size and microstructure on short crack development were studied.It was shown that the initiation process of fatigue cracks is that the damaged region is intensified gradually,and the growth of short cracks relates to the coalescence of cracks.The grain size and microstructure have a great influence upon the initiation and growth of short cracks.A reasonable definition was given in relation to short fatigue crack initiation and propagation.
关键词:
:fatigue damage
,
null
,
null
,
null
We CHEN
,
Zhanguo WANG
,
Zhaojun LIN
,
Yan XU and Lanying LIN(Lab. of Semiconductor Materials Sciences
,
Institute of Semiconductors
,
Chinese Academy of Sciences
,
Beijing 100083
,
China)
材料科学技术（英）
Two obvious emissions are observed from the ZnS clusters encapsulated in zeolite-Y. The emissionaround 355 nm is sharp and weak, locating at the onset of the absorption edge. The bandaround 535 nm is broad. Strong and Stokes-shifted. Both the two emissions shift to blue andtheir intensities firstly increase then decrease as the loading of ZnS in zeolite-Y or clusters sizedecreases. Through investigation, the former is attributed to the excitonic fluorescence, andthe latter to the trapped luminescence from surface States. The cluster size-dependence of theluminescence may be explained qualitatively by considering both the carrier recombination andthe nonradiative recombination rates. Four peaks appearing in the excitation spectra are assignedto the transitions of 1S-1S, 1S-1P, 1S-1D and sudsce state, respectively. The excitation spectraof the clusters do not coincide with their absorption spectra. The states splitted by quantum-sizeconfinement are detected in the excitation spectra, but could not be differentiated in the opticalabsorption spectra due to inhomogeneous broadening. The size-dependence of the excitationspectra is similar to that of the absorption spectra. Both the excitation spectra of excitonicand of trapped emissions are similar, but change in relative intensity and shift in position areobserved.
关键词:
Zhengfu WANG
,
Jin LI
,
Jianqiu WANG and Wei KE(Corrosion Science Laboratory
,
Institute of Corrosion and Protection of Metals
,
Chinese Academy of Sciences
,
Shenyang
,
110015
,
China)
材料科学技术（英）
The paper reports the effect of0.01,0.1 and 1%NaNO2, a passive inhibitor, on corrosion fatigue (CF) crack initiation and propagation for a low strength structural steel A537 in 3.5%NaCl aqueous solution. The experimental results show that inhibitor increases the required cycles of CF crack initiation effectively, and this effect increases with increasing inhibitor concentration.However, there is nearly no effect of NaNO2 on CF crack propagation. The same CF crack propagation rate was found in all kinds of solutions. The results also indicate that the passive time in 1%NaNO2 solution during plastic deformation is much longer than cyclic time. NaNO2 passivates the specimen sudece and repairs passive film damaged by cyclic loading during the crack initiation. while the passsive film is not formed fully due to continuous plastic deformation at the crack tip during the CF crack propagation, which is much different from that in the stress corrosion cracking and general corrosion
关键词:
Su'e LIU
,
Zhong ZHU and Wei KE(State Key Lab. of Corrosion and Protection
,
Institute of Corrosion and Protection of Metals
,
Chinese Academy of Sciences
,
Shenyang 110015
,
China) D.Hardie(Dept. of Mechanical
,
Materials and Manufacturing Engineering
,
Universi
材料科学技术（英）
Hydrogen embrittlement of Type 4340 steel has been investigated by straining round-notchedspecimens in 105 Pa hydrogen atmosphere at a constent cross-head spead of 1.4x 10-4 mm/s.The circumferentially notched specimens exhibited a significant embrittlement when their me-chanical behaviour in hydrogen was compared with that in air. Although the effect of notch depthon fracture strength in air is negligible, an increase in the depth of notch increase susceptibility toembrittlement when testing in gaseous hydrogen. However, analysis of the effects is complicatedby the facts that (i) the specimens show some degree of notch severity even when strained inair and (ii) the behaviour is complicated by the localised plastic deformation that may occur forrelatively shatlow notches. Such effects are eliminated at high stress concentration factors, sothere is a systematic loss in fracture stress in hydrogen as the notch sensitivity increases fromK=2.6 to 5.7 (where a 87% reduction of fracture stress occurs) but a relatively stable value isthen reached even for very severe notching bj fatigue pre-cracking. Whether or not the effectis due to increasing concentration of hydrogen in the triaxial stress region ahead of the notch,there is no doubt that increasing the stress concentration makes hydrogen more effective as anembrittlement agent.
关键词:
